The photochemically-induced rearrangement of some cyclohexa-2,4-dienones to bicyclo[3,1,0]hex-3-en-2-ones occurs by a general stereospecific ring opening to a keten, which is followed by a stereospecific thermal cyclisation.
M. R. Morris and A. J. Waring, J. Chem. Soc. D, 1969, 526 DOI: 10.1039/C29690000526
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