Issue 34, 2011

Methylenecyclopropane as C1 synthetic units: [1+4] cycloadditionvia a nickel catalyst

Abstract

Nickel-catalyzed reactions of methylenecyclopropanes and thioanhydrides afford sulfur-containing heterocyclic compoundsvia [1+4] cycloaddition. The reactions represent a new use for methylenecyclopropane as a possible one-carbon building block to replace carbon monoxide, isocyanides, and Fischer carbene complexes.

Graphical abstract: Methylenecyclopropane as C1 synthetic units: [1+4] cycloadditionvia a nickel catalyst

Supplementary files

Article information

Article type
Communication
Submitted
15 Jun 2011
Accepted
13 Jul 2011
First published
27 Jul 2011

Chem. Commun., 2011,47, 9711-9713

Methylenecyclopropane as C1 synthetic units: [1+4] cycloadditionvia a nickel catalyst

T. Inami, T. Kurahashi and S. Matsubara, Chem. Commun., 2011, 47, 9711 DOI: 10.1039/C1CC13540F

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