Issue 24, 2010
From the journal:

Organic & Biomolecular Chemistry

Total syntheses of the furanosesquiterpenes crassifolone and dihydrocrassifolone via an Au(i)-catalysed intramolecular Michael addition reaction†

Rajeev S. Menona  and  Martin G. Banwell*a  

* Corresponding authors

a Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, Australia
E-mail: mgb@rsc.anu.edu.au

Abstract

The racemic modifications of title natural products 1 and 2 have been synthesised for the first time. The key step was the Au(I)-catalysed conversion of the furanyl-substituted ynone 13 into the annulated furan 14.

Graphical abstract: Total syntheses of the furanosesquiterpenes crassifolone and dihydrocrassifolone via an Au(i)-catalysed intramolecular Michael addition reaction

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Article information

DOI
https://doi.org/10.1039/C0OB00487A
Article type
Communication
Submitted
26 Jul 2010
Accepted
13 Sep 2010
First published
07 Oct 2010

Org. Biomol. Chem., 2010,8, 5483-5485

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Total syntheses of the furanosesquiterpenes crassifolone and dihydrocrassifolone via an Au(I)-catalysed intramolecular Michael addition reaction

R. S. Menon and M. G. Banwell, Org. Biomol. Chem., 2010, 8, 5483 DOI: 10.1039/C0OB00487A

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