Issue 16, 2011
From the journal:

Dalton Transactions

Trinuclear rhodium hydride complexes†‡

Christian Fischer,a   Christina Kohrt,a   Hans-Joachim Drexler,a   Wolfgang Baumanna  and  Detlef Heller*a  

* Corresponding authors

a Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, Rostock, Germany
E-mail: detlef.heller@catalysis.de
Fax: (+49) 381-1281-51183
Tel: (+49) 381-1281-183

Abstract

Three novel trinuclear rhodium hydride complexes of the type {[Rh(PP*)H]3(μ2-H)3(μ3-H)}[BF4]2 containing diphosphines Tangphos, t-Bu-BisP* and Me-DuPHOS have been synthesised. The new compounds are very stable. Their structures have been characterized by X-ray analysis in the solid state and by NMR-spectroscopic investigations in solution.

Graphical abstract: Trinuclear rhodium hydride complexes

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Article information

DOI
https://doi.org/10.1039/C0DT01564D
Article type
Paper
Submitted
11 Nov 2010
Accepted
07 Feb 2011
First published
08 Mar 2011

Dalton Trans., 2011,40, 4162-4166

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Trinuclear rhodium hydride complexes

C. Fischer, C. Kohrt, H. Drexler, W. Baumann and D. Heller, Dalton Trans., 2011, 40, 4162 DOI: 10.1039/C0DT01564D

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