Issue 44, 2010
From the journal:

Dalton Transactions

On the nature of the transition metal–main group metal bond: synthesis and theoretical calculations on iridium gallyl complexes†

Clara J. Durango-García,a   J. Oscar C. Jiménez-Halla,b   Marcela López-Cardoso,a   Virginia Montiel-Palma,*a   Miguel A. Muñoz-Hernández*a  and  Gabriel Merino*b  

* Corresponding authors

a Centro de Investigaciones Químicas, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001 Col. Chamilpa, Cuernavaca, Morelos, México
E-mail: mamund2@.uaem.mx, vmontielp@ciq.uaem.mx
Fax: +52 777 3297997
Tel: +52 777 3297998

b Departamento de Química, División de Ciencias Naturales y Exactas, Universidad de Guanajuato, Col. Noria Alta s/n C.P., Guanajuato, Gto., México
E-mail: gmerino@quijote.ugto.mx
Fax: +52 473 7320006 ext. 8120
Tel: +52 473 7320006

Abstract

The iridum–gallyl complex MeIr(PCy3)2(GaMe2)(Cl˙GaMe3) exhibits a short Ir–Ga bond length of 2.381(1)–2.389(2) Å. Theoretical calculations (ZORA BP86/TZ2P) support the presence of a Ir–Ga single bond but highlight a π orbital contribution.

Graphical abstract: On the nature of the transition metal–main group metal bond: synthesis and theoretical calculations on iridium gallyl complexes

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Article information

DOI
https://doi.org/10.1039/C0DT01071E
Article type
Communication
Submitted
19 Aug 2010
Accepted
09 Sep 2010
First published
04 Oct 2010

Dalton Trans., 2010,39, 10588-10589

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On the nature of the transition metal–main group metal bond: synthesis and theoretical calculations on iridium gallyl complexes

C. J. Durango-García, J. O. C. Jiménez-Halla, M. López-Cardoso, V. Montiel-Palma, M. A. Muñoz-Hernández and G. Merino, Dalton Trans., 2010, 39, 10588 DOI: 10.1039/C0DT01071E

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