Issue 47, 2009
From the journal:

Physical Chemistry Chemical Physics

Equation of state for hard-sphere fluids offering accurate virial coefficients

Jianxiang Tian,*ac   Hua Jiang,b   Yuanxing Guic  and  A. Mulerod  

* Corresponding authors

a Shandong Provincial Key Laboratory of Laser Polarization and Information Technology Department of Physics, Qufu Normal University, Qufu, P. R. China

b Department of Physics, School of Science, Linyi Normal University, Linyi, P. R. China

c Department of Physics, Dalian University of Technology, Dalian, P. R. China
E-mail: jianxiangtian@yahoo.com.cn
Tel: 13406264707

d Department of Applied Physics, University of Extremadura, Badajoz 06072, Spain

Abstract

The asymptotic expansion method is extended by using currently available accurate values for the first ten virial coefficients for hard sphere fluids. It is then used to yield an equation of state for hard sphere fluids, which accurately represents the currently accepted values for the first sixteen virial coefficients and compressibility factor data in both the stable and the metastable regions of the phase diagram.

Graphical abstract: Equation of state for hard-sphere fluids offering accurate virial coefficients

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Article information

DOI
https://doi.org/10.1039/B915002A
Article type
Paper
Submitted
23 Jul 2009
Accepted
22 Sep 2009
First published
15 Oct 2009

Phys. Chem. Chem. Phys., 2009,11, 11213-11218

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Equation of state for hard-sphere fluids offering accurate virial coefficients

J. Tian, H. Jiang, Y. Gui and A. Mulero, Phys. Chem. Chem. Phys., 2009, 11, 11213 DOI: 10.1039/B915002A

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