Issue 13, 2009

Mechanistic insight into TEMPO-inhibited polymerisation: simultaneous determination of oxygen and inhibitor concentrations by EPR

Abstract

Convolution-based fitting of EPR spectra makes it possible to simultaneously determine concentrations of TEMPO and oxygen in TEMPO-inhibited polymerisations and autoxidations; this method is useful for understanding the chemistry of inhibitor mixtures.

Graphical abstract: Mechanistic insight into TEMPO-inhibited polymerisation: simultaneous determination of oxygen and inhibitor concentrations by EPR

Article information

Article type
Communication
Submitted
25 Mar 2009
Accepted
12 May 2009
First published
26 May 2009

Org. Biomol. Chem., 2009,7, 2685-2687

Mechanistic insight into TEMPO-inhibited polymerisation: simultaneous determination of oxygen and inhibitor concentrations by EPR

M. Conte, Y. Ma, C. Loyns, P. Price, D. Rippon and V. Chechik, Org. Biomol. Chem., 2009, 7, 2685 DOI: 10.1039/B905893A

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