Issue 33, 2007
From the journal:

Chemical Communications

Thermodynamically- and kinetically-controlled Friedel–Crafts alkenylation of arenes with alkynes using an acidic fluoroantimonate(v) ionic liquid as catalyst†

Doo Seong Choi,a   Jin Hong Kim,a   Ueon Sang Shin,a   Ravindra R. Deshmukha  and  Choong Eui Song*a  

* Corresponding authors

a Department of Chemistry, Institute of Basic Science, Sungkyunkwan University, Korea
E-mail: s1673@skku.edu
Fax: (+82) 31-290-7075
Tel: (+82) 31-290-5964

Abstract

By employing superacidic fluoroantimonate ionic liquid (IL), [bmim][Sb2F11], as catalyst, not only thermodynamically-controlled but also kinetically-controlled Friedel–Crafts alkenylations of arenes with alkynes have been realized for the first time.

Graphical abstract: Thermodynamically- and kinetically-controlled Friedel–Crafts alkenylation of arenes with alkynes using an acidic fluoroantimonate(v) ionic liquid as catalyst

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Article information

DOI
https://doi.org/10.1039/B705719A
Article type
Communication
Submitted
16 Apr 2007
Accepted
11 Jul 2007
First published
31 Jul 2007

Chem. Commun., 2007, 3482-3484

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Thermodynamically- and kinetically-controlled Friedel–Crafts alkenylation of arenes with alkynes using an acidic fluoroantimonate(V) ionic liquid as catalyst

D. S. Choi, J. H. Kim, U. S. Shin, R. R. Deshmukh and C. E. Song, Chem. Commun., 2007, 3482 DOI: 10.1039/B705719A

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