Issue 38, 2006
From the journal:

Chemical Communications

The synthesis, X-ray structure and fluxional behaviour of an ytterbium(ii) phenalenide complex

David J. Berg,*a   Jianlong Suna  and  Brendan Twamleyb  

* Corresponding authors

a Department of Chemistry, University of Victoria, P.O. Box 3065, Victoria, British Columbia, Canada
E-mail: djberg@uvic.ca, jianlong@uvic.ca
Fax: +1 250-721-7147
Tel: +1 250-721-7161

b University Research Office, 109 Morrill Hall, University of Idaho, Moscow, Idaho, USA
E-mail: btwamley@uidaho.edu
Fax: +1 208-885-6198
Tel: +1 208-885-2847

Abstract

The first lanthanoid complexes containing delocalized phenalenide anions are reported and the rapid migration of the η3-bonded metal centre between the three rings of the π-system is the first report of a degenerate haptotropic rearrangement in organolanthanoid chemistry.

Graphical abstract: The synthesis, X-ray structure and fluxional behaviour of an ytterbium(ii) phenalenide complex

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Article information

DOI
https://doi.org/10.1039/B609084B
Article type
Communication
Submitted
26 Jun 2006
Accepted
25 Jul 2006
First published
16 Aug 2006

Chem. Commun., 2006, 4019-4021

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The synthesis, X-ray structure and fluxional behaviour of an ytterbium(II) phenalenide complex

D. J. Berg, J. Sun and B. Twamley, Chem. Commun., 2006, 4019 DOI: 10.1039/B609084B

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