Issue 22, 2006
From the journal:

Chemical Communications

Simple transformation of crystalline chiral natural anions to liquid medium and their use to induce chirality†

Luís C. Branco,a   Pedro M. P. Gois,a   Nuno M. T. Lourenço,a   Vanya B. Kurtevaa  and  Carlos A. M. Afonso*b  

* Corresponding authors

a REQUIMTE, Departamento de Química, Faculdade de Ciências e Tecnologia da Universidade Nova de Lisboa, Quinta da Torre, Caparica, Portugal

b CQFM, Departamento de Engenharia Química e Biológica, Instituto Superior Técnico, Av. Rovisco Pais, Lisboa, Portugal
E-mail: carlosafonso@ist.utl.pt
Fax: (+) 351 218464455
Tel: (+) 351 218417627

Abstract

New chiral ionic liquids can be prepared simply by combining the tetra-n-hexyl-dimethylguanidinium cation with readily available chiral anions and used as an asymmetric inducing agent as demonstrated for catalytic Rh(II) carbenoid C–H insertion and Sharpless dihydroxylation.

Graphical abstract: Simple transformation of crystalline chiral natural anions to liquid medium and their use to induce chirality

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Article information

DOI
https://doi.org/10.1039/B600816J
Article type
Communication
Submitted
19 Jan 2006
Accepted
13 Apr 2006
First published
10 May 2006

Chem. Commun., 2006, 2371-2372

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Simple transformation of crystalline chiral natural anions to liquid medium and their use to induce chirality

L. C. Branco, P. M. P. Gois, N. M. T. Lourenço, V. B. Kurteva and C. A. M. Afonso, Chem. Commun., 2006, 2371 DOI: 10.1039/B600816J

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