Issue 108, 2005
From the journal:

CrystEngComm

Framework variations in Mn(ii)–organic coordination polymers: solvent templated formation and characterisation of 1D zigzag and straight chain network isomers†

Cheng-Bing Ma,a   Chang-Neng Chen*a  and  Qiu-Tian Liu*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
E-mail: lqt@ms.fjirsm.ac.cn

Abstract

Hydrothermal reaction of manganese carbonate with 4,4′-biphenyldicarboxylic acid (H2bda) and 1,10-phenanthroline (phen) affords coordination polymers, [Mn(bda)(phen)(H2O)]n·npy·nH2O (1·npy·nH2O, 1a), [Mn(bda)(phen)(H2O)]n·2npip (1·2npip, 1b) and [Mn(bda)(phen)]n (2). The polymer 1 crystallizes into either 1D zigzag chain or straight chain structures depending on the crystallisation solvents used, and both of them stack into a 3D guest-filled porous framework via inter-chain interactions, whereas the polymer 2 organizes into a 3D ligand-filled porous coordination framework in the absence of suitable guests. The polymer 1 represents an unusual example of network isomers formed via the templating of structurally dissimilar but closely related organic guests.

Graphical abstract: Framework variations in Mn(ii)–organic coordination polymers: solvent templated formation and characterisation of 1D zigzag and straight chain network isomers

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Article information

DOI
https://doi.org/10.1039/B511909J
Article type
Paper
Submitted
23 Aug 2005
Accepted
08 Nov 2005
First published
14 Nov 2005

CrystEngComm, 2005,7, 650-655

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Framework variations in Mn(II)–organic coordination polymers: solvent templated formation and characterisation of 1D zigzag and straight chain network isomers

C. Ma, C. Chen and Q. Liu, CrystEngComm, 2005, 7, 650 DOI: 10.1039/B511909J

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