A unique example of a 36 tessellated 2-D net based on a tri-nuclear zinc(II)-1,4-benzenedicarboxylate framework

Colleen A. Williams; Alexander J. Blake; Peter Hubberstey; Martin Schröder

doi:10.1039/B509929C

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A unique example of a 3⁶ tessellated 2-D net based on a tri-nuclear zinc(ii)-1,4-benzenedicarboxylate framework†

Colleen A. Williams,^a Alexander J. Blake,^a Peter Hubberstey*^a and Martin Schröder*^a

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* Corresponding authors

^a School of Chemistry, The University of Nottingham, Nottingham, UK
E-mail: Peter.Hubberstey@nottingham.ac.uk; M.Schroder@nottingham.ac.uk
Fax: + 44(0)115 9513563
Tel: + 44(0)115 9513490

Abstract

Reaction of Zn(NO₃)₂ and 1,4-benzenedicarboxylic acid (1,4-H₂BDC) at 100 °C for 24 hours in a pressure tube yielded on cooling {[Zn₃(1,4-BDC)₃(DEF)₂]·DEF}_∞ (DEF = diethylformamide) incorporating planar six-connected centres to give a unique 3⁶ tessellated 2-D framework polymer.

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Article information

DOI: https://doi.org/10.1039/B509929C
Article type: Communication
Submitted: 14 Jul 2005
Accepted: 06 Sep 2005
First published: 03 Oct 2005

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Chem. Commun., 2005, 5435-5437

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A unique example of a 3⁶ tessellated 2-D net based on a tri-nuclear zinc(II)-1,4-benzenedicarboxylate framework

C. A. Williams, A. J. Blake, P. Hubberstey and M. Schröder, Chem. Commun., 2005, 5435 DOI: 10.1039/B509929C

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Chemical Communications