Issue 12, 2005
From the journal:

Organic & Biomolecular Chemistry

“Click chemistry” en route to pseudo-starch

Laurence Marmuse,a   Sergey A. Nepogodiev*a  and  Robert A. Field*ab  

* Corresponding authors

a Centre for Carbohydrate Chemistry, School of Chemical Sciences and Pharmacy, University of East Anglia, Norwich, UK
E-mail: s.nepogodiev@uea.ac.uk

b Department of Biological Chemistry, John Innes Centre, Norwich, UK
E-mail: r.a.field@uea.ac.uk

Abstract

Rapid assembly of starch fragment analogues was achieved using “click chemistry”. Specifically, two hexadecasaccharide mimics containing two parallel maltoheptaosyl chains linked via [1,2,3]-triazoles to a maltose core were synthesized using Cu(I)-catalyzed [3 + 2] dipolar cycloaddition of azido saccharides and 6,6′- and 4′,6′-dipropargylated p-methoxyphenyl maltoside.

Graphical abstract: “Click chemistry” en route to pseudo-starch

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Article information

DOI
https://doi.org/10.1039/B504293C
Article type
Communication
Submitted
29 Mar 2005
Accepted
03 May 2005
First published
11 May 2005

Org. Biomol. Chem., 2005,3, 2225-2227

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“Click chemistry” en route to pseudo-starch

L. Marmuse, S. A. Nepogodiev and R. A. Field, Org. Biomol. Chem., 2005, 3, 2225 DOI: 10.1039/B504293C

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