Issue 18, 2004
From the journal:

Dalton Transactions

A new zincoborophosphate templated by diethylenetriamine (DETA): Synthesis and characterizations of (C4N3H16)[Zn3B3P6O24]·H2O†

Wei Liu,ab   Man-Rong Li,a   Hao-Hong Chen,a   Xin-Xin Yanga  and  Jing-Tai Zhao*a  

* Corresponding authors

a The State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Science, Shanghai, P. R. China
E-mail: jtzhao@mail.sic.ac.cn

b Graduate School of Chinese Academy of Science, Beijing, P. R. China

Abstract

The title zincoborophosphate was synthesized hydrothermally from a mixture of ZnO, B2O3, H3PO4 and the structure-directing amine, DETA. Its crystal structure contains helices made up of corner-sharing BO4 and PO4 tetrahedra, which interconnected with ZnO4 tetrahedra to form a three dimensional structure with the CZP topology. The amine and water molecules occupy the free thread of the helices and the center of the channels, respectively. Thermal stability investigations show that this new compound can be dehydrated at 423 K and the product is stable up to 723 K. Furthermore, the as-synthesized title compound and its dehydration product are luminescent, each with a similar broad band between 350 and 550 nm, but the emission of the latter is about three times more intense than that of the former.

Graphical abstract: A new zincoborophosphate templated by diethylenetriamine (DETA): Synthesis and characterizations of (C4N3H16)[Zn3B3P6O24]·H2O

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Article information

DOI
https://doi.org/10.1039/B407341J
Article type
Paper
Submitted
14 May 2004
Accepted
28 Jul 2004
First published
11 Aug 2004

Dalton Trans., 2004, 2847-2849

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A new zincoborophosphate templated by diethylenetriamine (DETA): Synthesis and characterizations of (C4N3H16)[Zn3B3P6O24]·H2O

W. Liu, M. Li, H. Chen, X. Yang and J. Zhao, Dalton Trans., 2004, 2847 DOI: 10.1039/B407341J

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