Issue 17, 2004
From the journal:

Physical Chemistry Chemical Physics

Carbon 1s photoelectron spectroscopy of six-membered cyclic hydrocarbons

V. M. Oltedal,a   K. J. Børve,*a   L. J. Sæthre,*a   T. D. Thomas,*b   J. D. Bozekc  and  E. Kukkd  

* Corresponding authors

a Department of Chemistry, University of Bergen, Bergen, Norway
E-mail: knut.borve@kj.uib.no

b Department of Chemistry, Oregon State University, Corvallis, Oregon, USA

c Advanced Light Source, Lawrence Berkeley National Laboratory, University of California, Berkeley, California, USA

d Department of Physical Sciences, University of Oulu, Oulu, Finland

Abstract

The carbon 1s photoelectron spectra of cyclohexane, cyclohexene, 1,3-cyclohexadiene, and 1,4-cyclohexadiene have been measured. These have been analyzed in terms of a theoretical model of the vibronic structure that includes the effects of the changes in equilibrium geometry that accompany core ionization as well as those of vibronic coupling in the core-ionized molecule. This theoretical approach gives an excellent description of the vibronic structure and makes it possible to identify the contributions of the inequivalent carbon atoms to the spectra. The carbon 1s ionization energies are reported and used in the analysis of photoelectron spectra of adsorbed molecules.

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Article information

DOI
https://doi.org/10.1039/B405109B
Article type
Paper
Submitted
05 Apr 2004
Accepted
16 Jun 2004
First published
09 Jul 2004

Phys. Chem. Chem. Phys., 2004,6, 4254-4259

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Carbon 1s photoelectron spectroscopy of six-membered cyclic hydrocarbons

V. M. Oltedal, K. J. Børve, L. J. Sæthre, T. D. Thomas, J. D. Bozek and E. Kukk, Phys. Chem. Chem. Phys., 2004, 6, 4254 DOI: 10.1039/B405109B

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