Issue 10, 2003

Synthetic study of optically active and C2-symmetric novel ligand, 7,8-bis(benzyloxy)bicyclo[2.2.2]octa-2,5-diene and a tricarbonyliron complex

Abstract

The 7,8-bis(benzyloxy)bicyclo[2.2.2]octa-2,5-diene derivatives have been synthesized via Diels–Alder reaction of optically active 5,6-bis(benzyloxy)cyclohexa-1,3-diene and dienophiles. The corresponding tricarbonyliron complexes have also been synthesized in enantiomerically pure form.

Graphical abstract: Synthetic study of optically active and C2-symmetric novel ligand, 7,8-bis(benzyloxy)bicyclo[2.2.2]octa-2,5-diene and a tricarbonyliron complex

Article information

Article type
Paper
Submitted
04 Feb 2003
Accepted
26 Mar 2003
First published
08 Apr 2003

Org. Biomol. Chem., 2003,1, 1726-1729

Synthetic study of optically active and C2-symmetric novel ligand, 7,8-bis(benzyloxy)bicyclo[2.2.2]octa-2,5-diene and a tricarbonyliron complex

A. Watanabe, M. Aso and H. Suemune, Org. Biomol. Chem., 2003, 1, 1726 DOI: 10.1039/B301271A

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