Issue 6, 2003
From the journal:

Chemical Communications

Formation of acetone enol on acidic zeolite ZSM-5 evidenced by H/D exchange

Mingcan Xu,a   Wei Wanga  and  Michael Hunger*a  

* Corresponding authors

a Institute of Chemical Technology, University of Stuttgart, Stuttgart, Germany
E-mail: michael.hunger@po.uni-stuttgart.de
Fax: +49 711 685-4081
Tel: +49 711 685-4079

Abstract

H/D exchange observed between bridging hydroxyl groups in acidic zeolite ZSM-5 and adsorbed acetone (acetone-d6/H-ZSM-5 and 13C-2-acetone/D-ZSM-5) indicates a concerted catalytic function of Brønsted acid sites and neighbouring framework oxygen atoms acting as Lewis base sites.

Graphical abstract: Formation of acetone enol on acidic zeolite ZSM-5 evidenced by H/D exchange

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Article information

DOI
https://doi.org/10.1039/B212701F
Article type
Communication
Submitted
23 Dec 2002
Accepted
06 Feb 2003
First published
18 Feb 2003

Chem. Commun., 2003, 722-723

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Formation of acetone enol on acidic zeolite ZSM-5 evidenced by H/D exchange

M. Xu, W. Wang and M. Hunger, Chem. Commun., 2003, 722 DOI: 10.1039/B212701F

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