Spontaneous resolution and absolute configuration of a coordination polymer formed by MnII and a ferrocene-based bisnitronyl nitroxide radical

Christian Sporer; Klaus Wurst; David B. Amabilino; Daniel Ruiz-Molina; Holger Kopacka; Peter Jaitner; Jaume Veciana

doi:10.1039/B205722K

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Spontaneous resolution and absolute configuration of a coordination polymer formed by Mn^II and a ferrocene-based bisnitronyl nitroxide radical†

Christian Sporer,^a Klaus Wurst,^a David B. Amabilino,^b Daniel Ruiz-Molina,^b Holger Kopacka,^a Peter Jaitner*^a and Jaume Veciana*^b

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* Corresponding authors

^a Institut für Allgemeine Anorganische und Theoretische Chemie, Universität Innsbruck, Innrain 52a , Austria
E-mail: Peter.Jaitner@uibk.ac.at
Fax: +43(0)512/507-2934
Tel: +43(0)512/507-5111

^b Institut de Ciència de Materials de Barcelona (CSIC), Campus Universitari, Bellaterra, Catalonia, Spain
E-mail: vecianaj@icmab.es
Fax: 34 93 5805729
Tel: 34 93 580 1853

Abstract

Crystallisation of a ferrocenyl bis(nitronyl nitroxide) with manganese(II) bis(hexafluoroacetylacetonate) gives rise to spontaneous resolution of a coordination polymer formed by the two units creating seven sources of chirality.

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Article information

DOI: https://doi.org/10.1039/B205722K
Article type: Communication
Submitted: 12 Jun 2002
Accepted: 29 Aug 2002
First published: 18 Sep 2002

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Chem. Commun., 2002, 2342-2343

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Spontaneous resolution and absolute configuration of a coordination polymer formed by Mn^II and a ferrocene-based bisnitronyl nitroxide radical

C. Sporer, K. Wurst, D. B. Amabilino, D. Ruiz-Molina, H. Kopacka, P. Jaitner and J. Veciana, Chem. Commun., 2002, 2342 DOI: 10.1039/B205722K

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