Issue 16, 2002

The frequency response of sorbate diffusion in one-dimensional channels

Abstract

The theoretical diffusion of ideal sorbate molecules along one-dimensional channels containing random sequences of high-energy and low-energy barriers has been studied. This situation might occur in the case of sorbate diffusion in one-dimensional zeolite channels containing two cationic species of different diameters attached to the aluminosilicate framework. Using a master equation with appropriate microscopic transfer rates characterising the transfer of sorbate molecules between neighbouring cells, the frequency response of the number of absorbed molecules to a periodic modulation of the sorbate concentration at the entrances to the channels has been calculated. For channels consisting of about 100 equal-height energy barriers the frequency response function agrees well with the continuum result obtained from the Fickian diffusion equation. Predictions for the frequency response functions when fast and slow microscopic transfer rates operate in each channel have been made. The presence of two distinct transfer rates gives rise to well-resolved low- and high-frequency features. The relevance of these results to experiments on porous materials is discussed.

Article information

Article type
Paper
Submitted
26 Apr 2002
Accepted
06 Jun 2002
First published
15 Jul 2002

Phys. Chem. Chem. Phys., 2002,4, 4071-4077

The frequency response of sorbate diffusion in one-dimensional channels

P. J. Camp, Phys. Chem. Chem. Phys., 2002, 4, 4071 DOI: 10.1039/B204015H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements