Issue 11, 2000
From the journal:

Chemical Communications

Synthesis of O-alkylhydroxylamines by electrophilic amination of alkoxides

Oliver F. Foota  and  David W. Knight*a  

* Corresponding authors

a Chemistry Department, Cardiff University, PO Box 912, Cardiff, UK
E-mail: knightdw@cf.ac.uk

Abstract

The 3-trichloromethyloxaziridine 7 reacts smoothly with lithium alkoxides, derived from a representative range of alcohols, transferring an NHBoc function to the oxygen to provide good to excellent yields of N-Boc-O-alkylhydroxylamines 8–16 by this new O-amination protocol.

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Article information

DOI
https://doi.org/10.1039/B002388O
Article type
Communication
Submitted
21 Mar 2000
Accepted
27 Apr 2000
First published
17 May 2000

Chem. Commun., 2000, 975-976

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Synthesis of O-alkylhydroxylamines by electrophilic amination of alkoxides

O. F. Foot and D. W. Knight, Chem. Commun., 2000, 975 DOI: 10.1039/B002388O

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