Allyltriethylgermane reacts with aldimines in preference to aldehydes by means of BF3•OEt2 and AcOH to afford homoallylic amines in high yields; three component syntheses of homoallytic amines starting from aldehyde, aniline and allylgermane were successfully achieved.
T. Akiyama, J. Iwai, Y. Onuma and H. Kagoshima, Chem. Commun., 1999, 2191 DOI: 10.1039/A907538K
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