Issue 19, 1999

Ferratricarbollide design for molecular assemblies: complexes [9,9′-(ButHN)2-commo-2,2′-M-closo-1,7,9-(C3B8H10)-1′,7′,9′-(C3B8H10)] (where M = Fe or Ru), the first examples of double-cluster metallatricarbollides

Abstract

The first types of double-cluster metallatricarbollides, compounds of general structure [9,9′-(ButHN)2-commo-2,2′-M-closo-1,7,9-(C3B8H10)-1′,7′,9′-(C3B8H10)] (for M = Fe or Ru), were synthesised from reactions between 7-(ButH2N)-7,8,9-C3B8H10 and FeCl2 or [RuCl2(DMSO)4] in the presence of excess NaH at high temperature; the complexes contain two amino groups conveniently attached in para-positions to the metal centres, which is a convenient feature for designed constructions of linear molecular assemblies.

Supplementary files

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1999, 3337-3338

Ferratricarbollide design for molecular assemblies: complexes [9,9′-(ButHN)2-commo-2,2′-M-closo-1,7,9-(C3B8H10)-1′,7′,9′-(C3B8H10)] (where M = Fe or Ru), the first examples of double-cluster metallatricarbollides

B. Grüner, F. Teixidor, C. Viñas, R. Sillanpää, R. Kivekäs and B. Štíbr, J. Chem. Soc., Dalton Trans., 1999, 3337 DOI: 10.1039/A905606H

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