The Diels–Alder reaction between various acrylates and cyclopentadiene in supercritical CO2 are catalysed by scandium tris(trifluoromethanesulfonate); optimisation of CO2 density leads to increased endo∶exo selectivities compared to those obtained in conventional solvents.
R. Scott Oakes, T. J. Heppenstall, N. Shezad, A. A. Clifford and C. M. Rayner, Chem. Commun., 1999, 1459 DOI: 10.1039/A904136B
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