Issue 4, 1999

Two amidine derivatives studied by 1H, 13C, 14N, 15N NMR and GIAO-CHF calculations

Abstract

1 H, 13C, 14N, and 15N NMR data are presented for two amidine derivatives and their complexes with TFA in 1:1 and 1∶2 molar ratios. The protonation site at the N5 atom was established based upon the observed coupling constants, NOE interactions, and chemical shift change. The GIAO-CHF calculations were also performed for the free bases and their N5 cations.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1999, 885-890

Two amidine derivatives studied by 1H, 13C, 14N, 15N NMR and GIAO-CHF calculations

J. W. Wiench, L. Stefaniak, E. Grech and E. Bednarek, J. Chem. Soc., Perkin Trans. 2, 1999, 885 DOI: 10.1039/A806259E

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