The utility of the cis-MCl2···HN+ chelated hydrogen bond as a synthon in preparation of crystalline [4,4′-H2bipy][MCl4] (M = Pd 1, Pt 2) is demonstrated; the structure of 2 contains anions and cations linked by hydrogen bonds to form a ribbon polymer.
G. R. Lewis, Chem. Commun., 1998, 1873 DOI: 10.1039/A804128H
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