Issue 5, 1998
From the journal:

Journal of the Chemical Society, Faraday Transactions

Transport and high-selectivity mechanisms of C 4 hydrocarbons through anhydrous Ag +-doped perfluorocarbon-type ion-exchange membranes

Wei Hu,   Kunihiro Adachi,   Hidetoshi Matsumoto  and  Akihiko Tanioka  

Abstract

Permeation experiments have been carried out for n-butane, but-1-ene and isobutene through anhydrous Ag +-doped perfluorosulfonate membranes from an AgBF 4 aqueous solution. The anhydrous Ag +-doped perfluorosulfonate membranes are microporous and n-butane flows through the microporous channels in these membranes in the gas phase. On the other hand, the transport of but-1-ene and isobutene is mainly controlled by hydrodynamic surface flow. Both the permeability of alkenes and the ideal selectivity of alkene/alkane increased with the increase in upstream gas pressure. The highest ideal separation factor is 2500 for but-1-ene/ n-butane and 810 for isobutene/ n-butane, indicating that anhydrous Ag +-doped PSM membranes are applicable for the separation of alkenes and alkanes. The ideal separation factor of 7.9 is also obtained for but-1-ene/isobutene.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/A707713K
Article type
Paper

J. Chem. Soc., Faraday Trans., 1998,94, 665-671

Permissions

Request permissions

Transport and high-selectivity mechanisms of C 4 hydrocarbons through anhydrous Ag +-doped perfluorocarbon-type ion-exchange membranes

W. Hu, K. Adachi, H. Matsumoto and A. Tanioka, J. Chem. Soc., Faraday Trans., 1998, 94, 665 DOI: 10.1039/A707713K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements