Inherently dinuclear iridium(III) meso architectures accessed by cyclometalation of calix[4]arene-based bis(aryltriazoles)

Stanislav Bezzubov; Kirill Ermolov; Alexander Gorbunov; Paulina Kalle; Ivan Lentin; Gennadij Latyshev; Vladimir Kovalev; Ivan Vatsouro

doi:10.1039/D1DT03579G

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Inherently dinuclear iridium(iii) meso architectures accessed by cyclometalation of calix[4]arene-based bis(aryltriazoles)†

Stanislav Bezzubov,

*^a Kirill Ermolov,

^b Alexander Gorbunov,

^b Paulina Kalle,

^a Ivan Lentin,

^b Gennadij Latyshev,^b Vladimir Kovalev

^b and Ivan Vatsouro

*^b

Author affiliations

* Corresponding authors

^a Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991 Moscow, Russia
E-mail: bezzubov@igic.ras.ru

^b Department of Chemistry M. V. Lomonosov Moscow State University, Lenin's Hills 1, 119991 Moscow, Russia
E-mail: vatsouro@petrol.chem.msu.ru

Abstract

Conventional cyclometalation of calix[4]arene bis(aryltriazoles) with iridium(III) chloride hydrate leads to unique meso architectures in which the Ir₂Cl₂ core is cross-bound by two (C^N)₂ ligands, which allows further replacement of the chloride bridges with ancillary ligands while maintaining the dinuclear structures of the complexes having independent or coupled iridium pairs.

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Article information

DOI: https://doi.org/10.1039/D1DT03579G
Article type: Paper
Submitted: 28 Sep 2021
Accepted: 27 Oct 2021
First published: 27 Oct 2021

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Dalton Trans., 2021,50, 16765-16769

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Inherently dinuclear iridium(III) meso architectures accessed by cyclometalation of calix[4]arene-based bis(aryltriazoles)

S. Bezzubov, K. Ermolov, A. Gorbunov, P. Kalle, I. Lentin, G. Latyshev, V. Kovalev and I. Vatsouro, Dalton Trans., 2021, 50, 16765 DOI: 10.1039/D1DT03579G

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Dalton Transactions

Inherently dinuclear iridium(iii) meso architectures accessed by cyclometalation of calix[4]arene-based bis(aryltriazoles)†

Abstract

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Inherently dinuclear iridium(III) meso architectures accessed by cyclometalation of calix[4]arene-based bis(aryltriazoles)

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