Na-related anodes with excellent rate capability and ultra-stable cyclability are being pursued significantly to overcome the slow kinetics of currently available compounds on account that the sodium-ion battery is an ideal energy storage device technology for grid-scale electricity networks. Herein, we demonstrate a novel concept for the construction of a nanoarchitecture with robust charge transfer networks, which is composed of MoS₂/C superstructure nanoflowers embedded in carbon nanonets (MoS₂/C-CNNs). Impressively, the optimized nanoarchitecture exhibited an ultra-fast Na-ion storage feature, a superior reversible capacity of 245.2 mA h g⁻¹ at 5 A g⁻¹, and a promising retention of 78.9% after 8000 cycles. The interconnected 3D carbon nanonetworks, derived from the carbonization of sugarcane bagasse via a novel “self-splitting process”, were found to be extremely beneficial for the acceleration of electron transport and Na⁺ diffusion, while alleviating the volumetric strain of MoS₂ during the Na⁺ insertion/extraction processes. Furthermore, computational analysis was performed to reveal the underlaid mechanism, demonstrating that the MoS₂/C superstructures can significantly ameliorate the electronic conductivity of MoS₂ and lower the Na⁺ diffusion barrier, which tend to facilitate the electron and Na⁺ transport at the atomic level. This work demonstrates that the construction of robust 3D ion/electron traffic networks at various scales is an efficient strategy to develop electrodes with adequate rate capability and remarkable cyclability.