Issue 2, 1996

Total synthesis of urdamycinone B via C-glycosidation of an unprotected sugar and Diels–Alder reaction of C-glycosyl juglone

Abstract

The total synthesis of C-glycosyl angucycline, urdamycinone B 1, was achieved via C-glycosidation of naphthol 6 and the unprotected D-olivose 7, and Diels–Alder reaction of the unprotected C-glycosyl juglone 9 and the diene 17 as the key steps.

Article information

Article type
Paper

Chem. Commun., 1996, 225-226

Total synthesis of urdamycinone B via C-glycosidation of an unprotected sugar and Diels–Alder reaction of C-glycosyl juglone

G. Matsuo, Y. Miki, M. Nakata, S. Matsumura and K. Toshima, Chem. Commun., 1996, 225 DOI: 10.1039/CC9960000225

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