Issue 50, 2013
From the journal:

Chemical Communications

Pyridine-based dicarbene ligand: synthesis and structure of a bis-2-pyridylidene palladium complex†

Tetsushi Yoshidomi,a   Yasutomo Segawa*a  and  Kenichiro Itamiab  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan
E-mail: ysegawa@nagoya-u.jp
Fax: +81-52-788-6098
Tel: +81-52-789-4525

b Institute of Transformative Bio-Molecules (WPI-ITbM), Nagoya University, Chikusa, Nagoya 464-8602, Japan

Abstract

We herein report the synthesis of a bis-2-pyridylidene palladium(II) complex as an isoelectronic structure of the well-known 2,2′-bipyridine complexes. One-pot or stepwise C–Cl oxidative addition followed by base-mediated C–H palladation of the chlorobipyridine dication to palladium(0) yielded the bis-2-pyridylidene palladium(II) carbonate smoothly.

Graphical abstract: Pyridine-based dicarbene ligand: synthesis and structure of a bis-2-pyridylidene palladium complex

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Article information

DOI
https://doi.org/10.1039/C3CC42655F
Article type
Communication
Submitted
11 Apr 2013
Accepted
01 May 2013
First published
01 May 2013

Chem. Commun., 2013,49, 5648-5650

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Pyridine-based dicarbene ligand: synthesis and structure of a bis-2-pyridylidene palladium complex

T. Yoshidomi, Y. Segawa and K. Itami, Chem. Commun., 2013, 49, 5648 DOI: 10.1039/C3CC42655F

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