Luminescent and coordinatively unsaturated heterobimetallic d10–d8 complexes. Photoredox properties and X-ray crystal structure of [AuPt(µ-dppm)2(CN)2]+[dppm = bis(diphenylphosphino)methane]
Abstract
The X-ray structure and photoredox properties of [AuPt(µ-dppm)2(CN)2]+ which has a long-lived (18 µs in acetonitrile at room temperature) and emissive excited state are described.