Issue 1, 1991

A new method for obtaining 1H NMR structural information on nitroxide spin labels through reduction to hydroxylamine by radiolysis of their methanolic solutions

Abstract

A preliminary description of a convenient method for the reduction of nitroxide spin labels by a radiolysis technique is described; the main advantage of this procedure is the ease with which nitroxides are converted to the corresponding non-paramagnetic hydroxylamines, the 1H NMR spectra of these hydroxylamines gives structural information on the parent spin labels.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 24-25

A new method for obtaining 1H NMR structural information on nitroxide spin labels through reduction to hydroxylamine by radiolysis of their methanolic solutions

M. E. Brik, H. Remita and M. O. Delcourt, J. Chem. Soc., Chem. Commun., 1991, 24 DOI: 10.1039/C39910000024

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