Issue 8, 1989

Synthesis and properties of a mercapto[15]annulenone: a 14π diatropic annulene triply characterised by a fast chemical exchange, tautomerisation, and cis-trans-isomerisation

Abstract

Mercapto[15]annulenone (4) has been prepared from annulenone (2) as a tautomeric mixture with the keto-tautomer (5) in 65% yield; it was found that (4) proved to be diatropic and exists as a rapid equilibrium mixture of (4a) and (4b).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 505-507

Synthesis and properties of a mercapto[15]annulenone: a 14π diatropic annulene triply characterised by a fast chemical exchange, tautomerisation, and cis-trans-isomerisation

H. Ogawa, M. Yoshikawa, H. Tanaka, T. Imoto, I. Miyamoto, H. Kato, Y. Taniguchi, Y. Nogami and T. Koga, J. Chem. Soc., Chem. Commun., 1989, 505 DOI: 10.1039/C39890000505

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