Issue 19, 1985

Bridge vs. terminal protonation of isostructural Mo–Pt and W–Pt heterobimetallic compounds

Abstract

Protonation of the complexes cp(OC)2[graphic omitted](CO)(PPh3)(cp = cyclopentadienyl) exhibits an M-dependent site selectivity, with protonation occurring at the metal–metal bond for M = Mo to give [cp(OC)2Mo(µ-PPh2)(µ-H)-Pt(CO)PPh3]+ whilst for M = W protonation occurs directly at he tungsten to give a terminal hydrido cation [cp-(OC)2H[graphic omitted](CO)PPh3]+.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 1312-1313

Bridge vs. terminal protonation of isostructural Mo–Pt and W–Pt heterobimetallic compounds

J. Powell, J. F. Sawyer and S. J. Smith, J. Chem. Soc., Chem. Commun., 1985, 1312 DOI: 10.1039/C39850001312

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