The primary kinetic deuterium isotope effect (PKIE) for the hydrogen atom abstraction from substituted phenols by polyvinyl acetate radical shows a large variation, and shows a maximum as a function of the reactivity of the compounds; the high values of PKIE may be attributed to tunnelling.
M. Simonyi, I. Fitos, J. Kardos, I. Lukovits and J. Pospišil, J. Chem. Soc., Chem. Commun., 1975, 252a DOI: 10.1039/C3975000252A
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