Issue 9, 1972
From the journal:

Journal of the Chemical Society, Chemical Communications

Self-exchange reactions of cobalt complexes and implications concerning redox reactivity of vitamin B12

D. Paul Rillema,   John F. Endicott  and  Noel A. P. Kane-Maguire  

Abstract

The self-exchange rates of Co(N4)(OH2)23+,2+ complexes, where (N4) is a tetradentate macrocyclic ligand, have been found to vary by a factor of 1010; the large reactivity range cannot be related to “spin effects”, but is likely a reflection of ligand reorganizational barriers; the vitamin B12a–B12r couple is at the high end of this range—a feature which has significance in the redox mechanisms of B12 and related systems.

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Article information

DOI
https://doi.org/10.1039/C39720000495
Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 495-496

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Self-exchange reactions of cobalt complexes and implications concerning redox reactivity of vitamin B12

D. P. Rillema, J. F. Endicott and N. A. P. Kane-Maguire, J. Chem. Soc., Chem. Commun., 1972, 495 DOI: 10.1039/C39720000495

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