Issue 37, 2010
From the journal:

Dalton Transactions

Isolation and characterization of a new type of μ-hydroxo-bis-Zn(salphen)assembly†

Daniele Anselmo,a   Eduardo C. Escudero-Adán,a   Jordi Benet-Buchholza  and  Arjan W. Kleij*ab  

* Corresponding authors

a Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, Tarragona, Spain
E-mail: akleij@iciq.es
Fax: +34 977920224
Tel: +34 977920247

b Institució Catalana de Recerca i Estudis Avançats (ICREA), Pg., LluísCompanys 23, Barcelona, Spain

Abstract

A series of assemblies comprising hydroxo-bridged dinuclear Zn(salphen) structures have been isolated and fully characterized in solution and by X-ray crystallography. The solution stability of these assembled species was evaluated in polar media, in the presence of excess of building blocks and competing ligands. The catalytic potential of this type of complex was investigated in phosphoester cleavage reactions.

Graphical abstract: Isolation and characterization of a new type of μ-hydroxo-bis-Zn(salphen) assembly

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Article information

DOI
https://doi.org/10.1039/C001801E
Article type
Paper
Submitted
27 Jan 2010
Accepted
27 Jul 2010
First published
18 Aug 2010

Dalton Trans., 2010,39, 8733-8740

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Isolation and characterization of a new type of μ-hydroxo-bis-Zn(salphen) assembly

D. Anselmo, E. C. Escudero-Adán, J. Benet-Buchholz and A. W. Kleij, Dalton Trans., 2010, 39, 8733 DOI: 10.1039/C001801E

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