Issue 20, 2008

Olefin isomerisation versus hydrozirconation: a case of a stable β-hydrogen-containing Zr-alkyl derivative

Abstract

Details of the olefin isomerisation mechanism followed by monohydride constrained-geometry zirconium complexes have been clarified using the allyldimethylsilylcyclopentadienyl zirconium hydride model compound. DFT calculations on the model systems agree with the experimental results.

Graphical abstract: Olefin isomerisation versus hydrozirconation: a case of a stable β-hydrogen-containing Zr-alkyl derivative

Supplementary files

Article information

Article type
Communication
Submitted
27 Feb 2008
Accepted
03 Mar 2008
First published
01 Apr 2008

Dalton Trans., 2008, 2670-2673

Olefin isomerisation versus hydrozirconation: a case of a stable β-hydrogen-containing Zr-alkyl derivative

C. E. Petrisor, L. M. Frutos, O. Castaño, M. E. G. Mosquera, E. Royo and T. Cuenca, Dalton Trans., 2008, 2670 DOI: 10.1039/B803419M

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