Issue 45, 2007
From the journal:

Chemical Communications

Solid-state luminescence switching of platinum(ii) dithiooxamide complexes in the presence of hydrogen halide and amine gases

Francesco Nastasi,a   Fausto Puntoriero,*a   Natale Palmeri,b   Stefano Cavallaro,b   Sebastiano Campagna*a  and  Santo Lanza*a  

* Corresponding authors

a Dipartimento di Chimica Inorganica, Chimica Analitica e Chimica Fisica, Università di Messina, Via Sperone 31, 98166 Messina, Italy
E-mail: campagna@unime.it (SC); lanza@unime.it (SL)
Fax: 39 090 393756

b Dipartimento di Chimica Industriale ed Ingegneria dei Materiali, Università di Messina, Via Sperone 31, 98166 Messina, Italy

Abstract

In the solid state, a non-luminescent platinum(II) dithiooxamide species adsorbs gaseous HCl, yielding a tight ion pair species which exhibits photoluminescence; the process is quantitatively reversed on heating or by exposing the sample to ammonia vapors.

Graphical abstract: Solid-state luminescence switching of platinum(ii) dithiooxamide complexes in the presence of hydrogen halide and amine gases

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Article information

DOI
https://doi.org/10.1039/B710372G
Article type
Communication
Submitted
09 Jul 2007
Accepted
13 Aug 2007
First published
11 Sep 2007

Chem. Commun., 2007, 4740-4742

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Solid-state luminescence switching of platinum(II) dithiooxamide complexes in the presence of hydrogen halide and amine gases

F. Nastasi, F. Puntoriero, N. Palmeri, S. Cavallaro, S. Campagna and S. Lanza, Chem. Commun., 2007, 4740 DOI: 10.1039/B710372G

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