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Photolysis of an alkoxyamine using intramolecular energy transfer from a quinoline antenna—towards photo-induced living radical polymerization

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Abstract

The photolysis of an alkoxyamine triad comprised of the 1-phenylethyl moiety, 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) and 2-methyl-3-hydroxy quinoline leads to energy transfer from the quinoline moiety (antenna) and cleavage of the C–O alkoxyamine bond, suggesting its possible applications in low temperature living free radical polymerization.

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Authors and Affiliations

  1. Institute for Chemical Research, Kyoto University, Uji, Kyoto, 611-0011, Japan

    Atsushi Goto

  2. Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Ontario, K1N 6N5, Canada

    J. C. Scaiano & Luca Maretti

Authors
  1. Atsushi Goto
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  2. J. C. Scaiano
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  3. Luca Maretti
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Goto, A., Scaiano, J.C. & Maretti, L. Photolysis of an alkoxyamine using intramolecular energy transfer from a quinoline antenna—towards photo-induced living radical polymerization. Photochem Photobiol Sci 6, 833–835 (2007). https://doi.org/10.1039/b705671k

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  • DOI: https://doi.org/10.1039/b705671k

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