Issue 9, 2001
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Low-temperature X-ray structural analysis of propanedinitrile derivatives substituted with a bis(4-dimethylaminophenyl)methyl group: the origin of elongation of the donor–acceptor substituted C–C bond†

Takanori Suzuki,*a   Kazunori Ono,a   Hidetoshi Kawaia  and  Takashi Tsujia  

* Corresponding authors

a Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo, Japan
E-mail: tak@sci.hokudai.ac.jp

Abstract

Push–pull type substitution at Csp3–Csp3 in the title compounds does not have special electronic effects on the bond length, and the observed expansion can be best accounted for by steric interaction between substituents.

Graphical abstract: Low-temperature X-ray structural analysis of propanedinitrile derivatives substituted with a bis(4-dimethylaminophenyl)methyl group: the origin of elongation of the donor–acceptor substituted C–C bond

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Article information

DOI
https://doi.org/10.1039/B103269K
Article type
Paper
Submitted
11 Apr 2001
Accepted
21 Jun 2001
First published
24 Jul 2001

J. Chem. Soc., Perkin Trans. 2, 2001, 1798-1801

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Low-temperature X-ray structural analysis of propanedinitrile derivatives substituted with a bis(4-dimethylaminophenyl)methyl group: the origin of elongation of the donor–acceptor substituted C–C bond

T. Suzuki, K. Ono, H. Kawai and T. Tsuji, J. Chem. Soc., Perkin Trans. 2, 2001, 1798 DOI: 10.1039/B103269K

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