Issue 6, 2001
From the journal:

Chemical Communications

Homologous families of chloride-rich 4,4′-bipyridinium salt structuresElectronic supplementary information (ESI) available: synthesis details for 1–4, crystal refinement details and colour structures for 1, 2 and 4. See http://www.rsc.org/suppdata/cc/b0/b009467f/

Ben Dolling,a   Amy L. Gillon,a   A. Guy Orpen,*a   Jonathan Starbucka  and  Xi-Meng Wanga  

* Corresponding authors

a School of Chemistry, University of Bristol, Cantock’s Close, Bristol, UK
E-mail: guy.orpen@bristol.ac.uk

Abstract

New layer and three-dimensional 4,4′-bipyridinium salts of Cl−, [MCl6]2− (M = Os, Pt) and [FeCl5]2− contain NH⋯(Cl)2⋯HN interactions which form hydrogen bonded ribbons which in turn give one-, two-, or three-dimensional periodic networks; two related families of homologous motifs are present in these salts together with those of square planar, polymeric and tetrahedral [MCl4]2− (M = Pt, Pd, Mn, Cd, Pb, Co, Zn, Hg), planar [Cu2Cl6]2− and square pyramidal [SbCl5]2− dianions.

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B009467F
Article type
Communication
Submitted
27 Nov 2000
Accepted
02 Feb 2001
First published
06 Mar 2001

Chem. Commun., 2001, 567-568

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Homologous families of chloride-rich 4,4′-bipyridinium salt structures

B. Dolling, A. L. Gillon, A. G. Orpen, J. Starbuck and X. Wang, Chem. Commun., 2001, 567 DOI: 10.1039/B009467F

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