Issue 24, 1999
From the journal:

Journal of the Chemical Society, Dalton Transactions

New compounds of tetradentate Schiff bases with vanadium(IV) and vanadium(V) †

Nosheen F. Choudhary,   Neil G. Connelly,   Peter B. Hitchcock  and  G. Jeffery Leigh  

Abstract

A new range of potentially tetradentate proligands, H2L, derived from aromatic aldehydes and ketones and aliphatic diamines has been prepared. Their vanadyl(IV) and vanadyl(V) complexes [VO(L)] and [VO(L)]+, and also some adducts [VO(L)→VO(L)]+, have been synthesized. The structures of four selected complexes have been determined and it is shown that these must be a result of both steric and electronic factors that make prediction of conformation and stacking difficult. The adducts [VO(L)→VO(L)]+ have structures that persist in solution in dichloromethane, where they can undergo redox chemistry, but they apparently dissociate into their component complexes in the donor solvent acetonitrile.

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Article information

DOI
https://doi.org/10.1039/A908337E
Article type
Paper

J. Chem. Soc., Dalton Trans., 1999, 4437-4446

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New compounds of tetradentate Schiff bases with vanadium(IV) and vanadium(V) †

N. F. Choudhary, N. G. Connelly, P. B. Hitchcock and G. Jeffery Leigh, J. Chem. Soc., Dalton Trans., 1999, 4437 DOI: 10.1039/A908337E

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