Issue 20, 1999

Arene catalysed sodium reactions

Abstract

2-Methyl-1-phenylpropan-1-ol and phenyltrimethylsilane were prepared in yields >85%, using naphthalene catalysed sodium reactions, whereby phenylsodium, prepared from the reaction of chlorobenzene, sodium powder and naphthalene (5%), was quenched with isobutyraldehyde or chlorotrimethylsilane respectively.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1999, 2869-2870

Arene catalysed sodium reactions

T. R. van den Ancker and M. J. Hodgson, J. Chem. Soc., Perkin Trans. 1, 1999, 2869 DOI: 10.1039/A907037K

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