Issue 4, 1985

The stereochemistry of oxidation of 1-amino-cyclopropanecarboxylic acid

Abstract

Whereas hypochlorite oxidation of 1-amino-cis-[2,3-2H2]cyclopropane carboxylic acid yields ethylene with retention of stereochemistry the use of transition metal oxidants, such as copper(II), permanganate, and ferrate ions gives completely scrambled cis- and trans-[1,2-2H2]ethylene as is found in the biosynthetic process.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 206-207

The stereochemistry of oxidation of 1-amino-cyclopropanecarboxylic acid

J. E. Baldwin, D. A. Jackson, R. M. Adlington and B. J. Rawlings, J. Chem. Soc., Chem. Commun., 1985, 206 DOI: 10.1039/C39850000206

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