Issue 0, 1980

Primary processes in the low-pressure pyrolysis of methylsilane

Abstract

The low-pressure pyrolysis of methylsilane in the unimolecular fall-off region proceeds mainly by formation of molecular hydrogen : MeSiH3→ MeSiH + H2; however, unimolecular formation of methane also occurs: MeSiH3→ SiH2+ CH4. Arrhenius parameters for both processes are estimated and some thermochemical deductions made.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1980,76, 1520-1525

Primary processes in the low-pressure pyrolysis of methylsilane

I. M. T. Davidson and M. A. Ring, J. Chem. Soc., Faraday Trans. 1, 1980, 76, 1520 DOI: 10.1039/F19807601520

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