Issue 0, 1972
From the journal:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

Comparison of the transport properties of normal and expanded forms of a cation-exchange membrane. Part 3.—Application of irreversible thermodynamics and Nernst-Planck theories to membranes in concentrated NaCl solutions

Colin R. Gardner  and  Russell Paterson  

Abstract

The Onsager mobility and frictional coefficients for the normal and expanded membranes have been calculated when the external solution was 1.0 M NaCl. The validity of a number of methods of approximation of minor coefficients is examined. The results have been reproduced using a ternary electrolyte calculation in which mobility coefficients for the salt-free membrane were combined with those of aqueous sodium chloride. Calculated transport measurements agree well with those obtained experimentally. Finally the validity and probable errors of the Nernst-Planck theory are examined.

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Article information

DOI
https://doi.org/10.1039/F19726802030
Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1972,68, 2030-2040

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Comparison of the transport properties of normal and expanded forms of a cation-exchange membrane. Part 3.—Application of irreversible thermodynamics and Nernst-Planck theories to membranes in concentrated NaCl solutions

C. R. Gardner and R. Paterson, J. Chem. Soc., Faraday Trans. 1, 1972, 68, 2030 DOI: 10.1039/F19726802030

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