Issue 7, 1986
From the journal:

Journal of the Chemical Society, Dalton Transactions

Actinide structural studies. Part 10. A mixed oxidation state neptunyl chloride: crystal structure of Cs7[NpVO2][NpVIO2]2Cl12

Nathaniel W. Alcock,   David J. Flanders  and  David Brown  

Abstract

The crystal structure of Cs7[NpVO2][NpVIO2]2Cl12 has been determined. It is cubic, with a= 15.084(4)Å, space group I[4 with combining macron]3d, and R= 0.035 for 1 674 observed [I/σ(I)[gt-or-equal] 3.0] reflections. Only one neptunium position is found, containing two NpVI and one NpV, substitutionally disordered. They are octahedrally co-ordinated, with Np–O 1.790(15) and Np–Cl 2.685(5)Å, intermediate between the values for NpV and NpVI.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9860001403
Article type
Paper

J. Chem. Soc., Dalton Trans., 1986, 1403-1404

Permissions

Request permissions

Actinide structural studies. Part 10. A mixed oxidation state neptunyl chloride: crystal structure of Cs7[NpVO2][NpVIO2]2Cl12

N. W. Alcock, D. J. Flanders and D. Brown, J. Chem. Soc., Dalton Trans., 1986, 1403 DOI: 10.1039/DT9860001403

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements