High-field vanadium-51 and oxygen-17 nuclear magnetic resonance study of peroxovanadates(V)
Abstract
High-field 51V and 17O n.m.r. spectroscopy has clarified the aqueous chemistry of the peroxovanadates, leading to the identification of five new species, four of which are dimeric, Mono- and di-peroxovanadates undergo a change of co-ordination from octahedral to tetrahedral when their final proton is removed.