Volume 87, 1989
From the journal:

Faraday Discussions of the Chemical Society

Adsorption and reactions of ethyne. Effects of modifiers and formation of bimetallics

Nicolaas R. M. Sassen,   Adrianus J. den Hartog,   Fred Jongerius,   Jacques F. M. Aarts  and  Vladimir Ponec  

Abstract

Adsorption of C2H2 and C2H4 has been studied with Pd(111) and Pd–Cu(111) single-crystal planes using EELS. The formation of dissociatively adsorbed species is controlled by ensemble size effects. The catalytic experiments performed with powder catalysts reveal that formation of bimetallics from an active and an inactive metal or diminishing the particle size increase the selectivity to ethene. This supports the idea that the increase is due to suppression of dissociatively adsorbed, possibly multiply bound, species.

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Article information

DOI
https://doi.org/10.1039/DC9898700311
Article type
Paper

Faraday Discuss. Chem. Soc., 1989,87, 311-320

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Adsorption and reactions of ethyne. Effects of modifiers and formation of bimetallics

N. R. M. Sassen, A. J. den Hartog, F. Jongerius, J. F. M. Aarts and V. Ponec, Faraday Discuss. Chem. Soc., 1989, 87, 311 DOI: 10.1039/DC9898700311

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